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CHLORHEXIDINE DIACETATE.

Valuable CAS 56-95-1 / ANTIMICROBIAL, ORAL CARE, PRESERVATIVE

A broad-spectrum cationic antimicrobial agent, Chlorhexidine Diacetate functions primarily as a preservative in cosmetics. It also provides antibacterial properties suitable for various topical applications.

Antimicrobial/antibacterial Preservative Oral care

Science

It destabilizes bacterial cell membranes by attracting to negatively charged components, leading to leakage of intracellular contents. This dual action results in both bactericidal and bacteriostatic effects, effectively eliminating bacteria.


Research

High confidence
Effective range 0.01–0.19%
Optimal

N/A

Key findings

  1. 01 The CIR Expert Panel concluded it is safe for cosmetic use up to 0.19% concentration.
  2. 02 Market surveys show concentrations between 0.01% and 0.15% in various cosmetic product types.

Transparency

Not commonly dusted

The Formula

Solubility
Water
Optimal pH 5 – 8
0 7 14

Stability

Aqueous solutions are most stable between pH 5-8, with activity deteriorating in more acidic conditions and precipitation above pH 8. Avoid prolonged heat above 70 °C and light.

Conflicts

  • Anionic agents/surfactants (e.g., carbomer, sodium lauryl sulfate) can lead to inactivation or precipitation.
  • Other incompatibilities include sodium hypochlorite, EDTA, saline, and ethanol, which may cause precipitation.

Safety

CIR Status
Safe with restrictions
Max tested
0.19%
Sensitization risk Moderate

The CIR considers it safe up to 0.19% in cosmetics, while the EU allows up to 0.3% as a preservative. The FDA has noted rare serious allergic reactions with related chlorhexidine salts.


Your Skin

No Normal
No Dry
No Oily
No Sensitive
Irritancy Medium
Comedogenicity Unknown

Our Assessment

Valuable

Chlorhexidine Diacetate is a valuable antimicrobial preservative for cosmetics, though its medium irritancy potential necessitates careful formulation and concentration control.


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