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CETYL BETAINE.

Valuable CAS 693-33-4 / ANTISTATIC, CLEANSING, HAIR CONDITIONING, SKIN CONDITIONING, SURFACTANT - CLEANSING, SURFACTANT - FOAM BOOSTING, VISCOSITY CONTROLLING

A high-performance zwitterionic surfactant that provides gentle cleansing while enhancing the structural integrity of the formula's texture. Unlike harsher detergents, it maintains skin barrier health by reducing the irritation potential of other surfactants.

Surfactant Cleansing Agent Viscosity Controller Skin Conditioning Antistatic Agent

Science

Cetyl Betaine operates as an amphoteric molecule featuring a 16-carbon hydrophobic chain that efficiently emulsifies lipids and debris. Its most distinctive function is its ability to form mixed micelles with anionic surfactants like SLS, effectively 'masking' their charge and preventing them from penetrating deep into the stratum corneum, thereby acting as a counter-irritant.


Research

High confidence
Effective range 0.5–8.8%
Optimal

5%

Key findings

  1. 01 In vivo human testing confirms that at concentrations up to 5.4 mM, the ingredient partitions into the outer stratum corneum without increasing transepidermal water loss (TEWL).
  2. 02 Phase I dose-escalation studies demonstrate significantly lower mucosal and skin irritation potential compared to traditional surfactants like Nonoxynol-9.

Transparency

Not commonly dusted
Min. effective
0.5%
Red flag below
0.1%

Because it is a functional surfactant and viscosity builder, it is rarely 'dusted' at negligible levels; however, levels below 0.5% in a primary cleanser may indicate it is being used merely for label claims rather than functional mildness.


The Formula

Solubility
Water
Optimal pH 3 – 7
0 7 14

Stability

Exhibits exceptional thermal stability, remaining unchanged at 135°C for 30 days. It maintains its zwitterionic character across a broad range but is most stable between pH 3 and 7.

Synergies

  • Anionic surfactants (reduces their irritation profile)
  • Cationic conditioners
  • Non-ionic emulsifiers

Conflicts

  • High electrolyte concentrations (may cause salting out)

Safety

CIR Status
Safe as used
Max tested
8.8%
Pregnancy
Safe
Sensitization risk Low

The CIR Expert Panel considers it safe in rinse-off applications up to 8.8%. It is specifically noted for its low irritation potential in sensitive areas.


Your Skin

Yes Normal
Yes Dry
Yes Oily
Yes Sensitive
Irritancy Low
Comedogenicity Low

Our Assessment

Valuable

An excellent secondary surfactant that upgrades formula mildness and texture without compromising cleansing efficacy.


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References