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CETEARETH-4 PHOSPHATE.

Valuable CAS 106233-09-4 / CLEANSING, SURFACTANT - CLEANSING

An advanced anionic emulsifier and surfactant that bridges the gap between oil and water phases to create sophisticated, lamellar liquid crystalline structures. Its unique phosphate-based chemistry allows for the seamless stabilization of pigments and UV filters, resulting in superior product texture and uniform skin application.

emulsifying surfactant cleansing stabilizing

Science

It functions as a surface-active agent that adsorbs at the oil-water interface, drastically reducing surface tension to prevent emulsion separation. By organizing into lamellar structures, it mimics the skin's natural lipid bilayer, which enhances the stability of the formulation while ensuring that active ingredients and minerals are evenly dispersed across the stratum corneum.


Research

High confidence
Effective range 1–5%
Optimal

1.5%

Key findings

  1. 01 Safety assessments by the CIR indicate that Ceteareth-n family members are non-sensitizers and produce minimal irritation in both acute and long-term (21-day) patch testing.
  2. 02 Structural analogs tested at concentrations up to 10% demonstrate a high safety profile with only minimal dermal irritation observed.
  3. 03 Rare clinical reports of contact dermatitis have been noted with related phosphate esters (Triceteareth-4 Phosphate), emphasizing the importance of high-purity sourcing.

Transparency

Not commonly dusted
Min. effective
0.5%
Red flag below
0.2%

As a functional emulsifier, it is rarely 'dusted' for marketing purposes. It is typically included at the precise levels (1-5%) required to achieve emulsion stability and pigment suspension.


The Formula

Solubility
Both
Optimal pH 3 – 9
0 7 14

Stability

Exhibits exceptional thermal stability and maintains integrity across a broad pH spectrum. It shows high electrolyte tolerance (up to 1% NaCl), making it ideal for complex formulas.

Synergies

  • UV filters
  • Polar oils
  • Mineral pigments

Conflicts

  • Strong cationic surfactants
  • Concentrated polyvalent metal ions

Safety

CIR Status
Safe as used
Max tested
5%
Pregnancy
Safe
Sensitization risk Low

Safety is contingent on minimizing the impurity 1,4-dioxane; Moumoujus standards require levels below 1 ppm, exceeding the standard safety threshold of 10 ppm.


Your Skin

Yes Normal
Yes Dry
Yes Oily
Yes Sensitive
Irritancy Low
Comedogenicity Low

Our Assessment

Valuable

A highly stable and skin-compatible emulsifier essential for creating elegant, uniform dispersions of sunscreens and pigments.


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References