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CETALKONIUM CHLORIDE.

Valuable CAS 122-18-9 / ANTIMICROBIAL, ANTISTATIC, PRESERVATIVE

A high-performance cationic quaternary ammonium compound that utilizes electrostatic attraction to bond with the skin's surface. In precision skincare, it functions as a potent antimicrobial stabilizer and a bio-adhesive agent that enhances the longevity of active ingredients on the cutaneous layer.

Antimicrobial Bio-adhesive Preservative Emulsion Stabilizer

Science

As a cationic surfactant, it generates a positive zeta potential (approximately +40mV), allowing it to anchor to the negatively charged surfaces of the skin and ocular epithelium. This bio-adhesion facilitates superior drug delivery while simultaneously disrupting microbial cell membranes and denaturing proteins to provide antiseptic benefits.


Research

High confidence
Effective range 0.005–3%
Optimal

0.1%

Key findings

  1. 01 At a 0.1% concentration, it demonstrated superior antimicrobial efficacy in wound environments compared to standard saline solutions.
  2. 02 Usage at 0.005% in nanoemulsions significantly increases the residence time and bioavailability of active compounds through electrostatic bio-adhesion.

Transparency

Commonly dusted
Min. effective
0.01%
Red flag below
0.001%

Because it is effective as a preservative and stabilizer at concentrations as low as 0.005%, it is frequently included in formulations for technical stability rather than clinical skin benefits. For genuine antimicrobial or bio-adhesive efficacy, levels should typically reach 0.05% to 0.1%.


The Formula

Solubility
Oil
Optimal pH 5 – 7.5
0 7 14

Stability

Highly lipophilic (logP ~9.5) and remarkably stable in nanoemulsions. Unlike other benzalkonium derivatives, it does not migrate easily into the aqueous phase, ensuring structural integrity of oil-in-water systems.

Synergies

  • Cationic nanoemulsions
  • Lipid-based delivery systems

Conflicts

  • Anionic surfactants
  • Strong oxidizing agents
  • Nitrosating agents
  • Carboxylic acid esters

Safety

CIR Status
Safe with restrictions
Max tested
3%
Pregnancy
Safe
Sensitization risk Moderate

While generally safe, its use is strictly regulated: 0.1% as a preservative and up to 3% in rinse-off applications. Avoid use on compromised skin at high concentrations due to its medium irritancy potential.


Your Skin

Yes Normal
Yes Dry
Yes Oily
No Sensitive
Irritancy Moderate
Comedogenicity Low

Our Assessment

Valuable

A sophisticated delivery-enhancing agent best utilized in precision nanoemulsions to increase the contact time of active ingredients with the skin.


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