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CAPTAN.

Avoid CAS 133-06-2 / ANTIMICROBIAL

Captan is a chlorinated organosulfur compound historically used in personal care for its potent antimicrobial and antifungal properties. Once a staple in medicated hair care, it has transitioned almost exclusively to agricultural use due to regulatory prohibitions in global cosmetic markets.

antimicrobial antifungal preservative

Science

Captan functions as a non-specific thiol reactant. It disrupts microbial life by covalently binding to sulfhydryl (-SH) groups in both proteins and non-protein cellular components. This action effectively shuts down the Krebs cycle and inhibits cellular respiration, preventing fungi and bacteria from producing energy or reproducing.


Research

Medium confidence
Effective range 0.5–1%
Optimal

1%

Key findings

  1. 01 Established as the benchmark concentration for mitigating dandruff and serving as a bacteriostatic agent in liquid soaps.
  2. 02 Identified as the upper limit for topical tolerance in preservative testing, though skin sensitization was still observed at this level.

Transparency

Not commonly dusted
Red flag below
0.01%

Because Captan is a prohibited substance in most major markets (EU, Canada, ASEAN), its presence at any concentration in modern skincare is a regulatory red flag rather than a 'dusting' issue.


The Formula

Solubility
Oil
Optimal pH 5.5 – 6.5
0 7 14

Stability

Highly sensitive to alkaline environments; the molecule undergoes rapid hydrolysis when pH exceeds 7.0. It requires slightly acidic conditions for structural integrity.

Conflicts

  • Alkaline ingredients
  • Strong bases
  • Strong oxidizing agents
  • Sulfhydryl-containing compounds

Safety

CIR Status
Insufficient data
Max tested
0%
Pregnancy
Caution
Sensitization risk High

Prohibited for cosmetic use in the EU, Canada, and ASEAN. While the EPA has moderated its carcinogenicity classification for residential use, its high potential for irritancy and sensitization led the CIR to deem existing safety data insufficient.


Your Skin

No Normal
No Dry
No Oily
No Sensitive
Irritancy High
Comedogenicity Unknown

Our Assessment

Avoid

Due to its prohibited regulatory status and high risk of skin sensitization, Captan is unsuitable for modern precision skincare.


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