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Caprolactam.

Optional CAS 105-60-2 / NOT REPORTED

Caprolactam is a versatile synthetic compound primarily utilized as a structural building block for advanced film-formers and skin-conditioning agents. In precision skincare, it serves as a dual-purpose molecule that enhances the delivery of active ingredients while providing a flexible, breathable barrier for the skin surface.

Skin conditioning Film forming Antistatic Penetration enhancer Solvent

Science

Caprolactam functions by momentarily reorganizing the lipid architecture of the stratum corneum, allowing for deeper penetration of both hydrophilic and lipophilic actives. Additionally, when integrated into polymer structures like Nylon-6, it creates a smoothing antistatic film that stabilizes the skin’s microenvironment and prevents moisture loss.


Research

Medium confidence
Effective range 1–15%
Optimal

1%

Key findings

  1. 01 In vitro porcine skin models indicate that caprolactam-derived ionic liquids significantly outperform traditional penetration enhancers (like Azone) at concentrations between 10-15%.
  2. 02 Safety evaluations confirm that residual monomer levels below 1% in cosmetic polymers are non-sensitizing and effective for maintaining film integrity without irritation.

Transparency

Commonly dusted
Min. effective
0.1%
Red flag below
0.05%

Because caprolactam is often present only as a residual byproduct of polymer manufacturing (like Nylon-6) rather than a deliberate active, it is frequently 'dusted' in ingredient lists at negligible levels that provide no real penetration enhancement.


The Formula

Solubility
Water
Optimal pH 5 – 8
0 7 14

Stability

Highly hygroscopic and stable in neutral environments; however, it is prone to hydrolysis into 6-aminohexanoic acid if exposed to strong mineral acids.

Synergies

  • Hydrophilic actives
  • Film-forming polymers
  • Nylon-6

Conflicts

  • Strong mineral acids
  • Strong oxidizing agents
  • Strong bases

Safety

CIR Status
Safe as used
Max tested
1%
Sensitization risk Moderate

Safe for cosmetic use when restricted to levels under 1% within polymer complexes. Pure, standalone caprolactam is a known skin irritant and is restricted in high-concentration topical applications.


Your Skin

Yes Normal
Yes Dry
Yes Oily
No Sensitive
Irritancy Moderate
Comedogenicity Low

Our Assessment

Optional

A specialized penetration enhancer and film precursor that is valuable for texture and delivery, provided it is formulated within strict safety thresholds.


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