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CALCIUM CITRATE.

Valuable CAS 813-94-5 / BUFFERING

A precision-engineered mineral salt that acts as a vital architectural stabilizer for the skin's barrier. It functions as a sophisticated pH buffer while providing essential calcium ions necessary for the structural integrity of the stratum corneum.

pH Buffering Barrier Repair Cell Signaling Skin Conditioning

Science

It restores the epidermal calcium gradient, a crucial signaling mechanism that directs keratinocytes to transform into mature barrier cells. By triggering the release of lamellar bodies, it facilitates the delivery of essential lipids and enzymes to the skin surface, while simultaneously maintaining the acid mantle's protective pH range.


Research

High confidence
Effective range 0.1–5%
Optimal

1%

Key findings

  1. 01 Regulates keratinocyte differentiation and lamellar body secretion to optimize barrier function at concentrations of 0.1-1.0% (Lee et al., 2018).
  2. 02 Demonstrated significant protective capabilities against oxidative stress and improved cellular viability in epidermal cells when utilized at 5.0% in nanoparticle delivery systems (Bukkavesa et al., 2019).

Transparency

Commonly dusted
Min. effective
0.1%
Red flag below
0.05%

Because it is often used as a simple pH adjuster, many brands include it at negligible levels (<0.05%) for label claims regarding 'barrier support' without providing the ionic concentration necessary to influence the calcium gradient.


The Formula

Solubility
Water
Optimal pH 3 – 6.2
0 7 14

Stability

Solubility is highly pH-dependent; it remains stable and soluble in acidic environments but carries a risk of precipitation as the formulation approaches a neutral or alkaline pH (>7.0).

Synergies

  • Alpha Lipoic Acid
  • Alginates
  • Barrier Lipids

Conflicts

  • Carbomers (causes immediate loss of viscosity)
  • Fluoride ions
  • Phosphate salts
  • High pH systems

Safety

CIR Status
Safe as used
Max tested
10%
Pregnancy
Safe
Sensitization risk Low

Recognized as GRAS (Generally Recognized as Safe) by the FDA; clinical reviews confirm a very low potential for irritation even in sensitive applications.


Your Skin

Yes Normal
Yes Dry
Yes Oily
Yes Sensitive
Irritancy Low
Comedogenicity Low

Our Assessment

Valuable

An essential mineral tool for maintaining the skin's acidic equilibrium and signaling structural barrier repair.


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