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CALCIUM BENZOATE.

Valuable CAS 2090-05-3 / PRESERVATIVE

Calcium Benzoate is a high-performance preservative salt used to maintain the integrity and microbiological safety of aqueous cosmetic formulations. It serves as a critical guardian against spoilage, ensuring that precision skincare remains stable and effective throughout its shelf life.

preservative antimicrobial

Science

It functions by penetrating the cell walls of harmful microorganisms and lowering their internal pH. This acidification inhibits key metabolic enzymes, such as phosphofructokinase, effectively halting the glycolytic pathway and preventing the proliferation of bacteria, yeasts, and molds.


Research

High confidence
Effective range 0.002–5%
Optimal

0.5%

Key findings

  1. 01 The CIR Expert Panel confirmed the safety of benzoate salts in concentrations up to 5% (expressed as benzoic acid), noting they are non-sensitizing.
  2. 02 Regulatory assessments by the SCCS validated the efficacy of benzoate salts as preservatives at 1.7% in oral care and up to 2.5% in rinse-off formulations.
  3. 03 Industry surveys indicate that even at ultra-low concentrations (0.002-0.004%), it provides meaningful support to complex preservative systems without skin irritation.

Transparency

Not commonly dusted
Min. effective
0.1%
Red flag below
0.002%

As a preservative, it is intentionally used at low concentrations; however, formulations using less than 0.01% may be 'dusting' the ingredient for label claims rather than achieving robust antimicrobial protection.


The Formula

Solubility
Water
Optimal pH 2.5 – 5.5
0 7 14

Stability

Stability is highest in acidic environments where it exists in its active, undissociated form. Antimicrobial efficacy drops significantly when the formulation pH rises above 6.0.

Synergies

  • Organic acids
  • Chelating agents

Conflicts

  • Non-ionic surfactants
  • Strongly alkaline ingredients
  • Ferric salts

Safety

CIR Status
Safe as used
Max tested
5%
Pregnancy
Safe
Sensitization risk Low

While CIR allows up to 5%, EU regulations are stricter, limiting use to 0.5% in leave-on products and 2.5% in rinse-off products.


Your Skin

Yes Normal
Yes Dry
Yes Oily
Yes Sensitive
Irritancy Low
Comedogenicity Low

Our Assessment

Valuable

A safe, reliable, and non-irritating preservative essential for maintaining the purity of water-based skincare.


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