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C4-14 PERFLUOROALKYLETHOXY DIMETHICONE.

Valuable / SKIN CONDITIONING

A high-performance fluorinated silicone polymer that functions as both a skin conditioner and a sophisticated film-former. It creates a breathable, refractive shield on the skin surface to provide exceptional resistance to both water and oil while delivering a non-greasy, satin-like finish.

Skin conditioning Film forming Barrier protection Oil repellency Water repellency

Science

By integrating perfluoroalkyl groups (C4-14) onto a dimethicone backbone, this molecule exhibits dual-repellency: it is both hydrophobic (water-repelling) and oleophobic (oil-repelling). This unique chemistry establishes a resilient yet breathable barrier that minimizes transepidermal water loss (TEWL), shields the skin from particulate environmental pollutants, and prevents the migration of cosmetic pigments or sebum.


Research

Medium confidence
Effective range N/A
Optimal

N/A

Key findings

  1. 01 Indicated by the FDA as a skin protectant that forms a refractive barrier to prevent exogenous substance entry.
  2. 02 Demonstrated high oil and water repellency in long-wear formulations, significantly contributing to transfer resistance.

Transparency

Not commonly dusted

As a functional polymer rather than a bio-active ingredient, it is typically included at levels required for specific film-forming performance rather than 'dusted' for marketing claims.


The Formula

Solubility
Oil
Optimal pH 3 – 10
0 7 14

Stability

Highly chemically inert and stable across a broad pH spectrum. It must be dispersed within the silicone phase and is specifically miscible with dimethicone and cyclopentasiloxane.

Synergies

  • Cyclopentasiloxane
  • Dimethicone
  • Mineral UV filters

Conflicts

  • Water
  • Strong acids
  • Strong alkalis
  • Non-polar hydrocarbon oils

Safety

CIR Status
Safe as used
Sensitization risk Low

While considered safe for skin application by the CIR Expert Panel, this ingredient belongs to the PFAS class, leading to its phase-out by certain retailers due to environmental persistence concerns.


Your Skin

Yes Normal
Yes Dry
Yes Oily
Yes Sensitive
Irritancy Low
Comedogenicity Low

Our Assessment

Valuable

An elite functional agent for achieving superior transfer resistance and environmental protection, though its PFAS classification may limit its future availability in sustainable portfolios.


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References