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C18-22 ALKYL PEG-25 METHACRYLATE/DIETHYLAMINOETHYL METHACRYLATE COPOLYMER.

Valuable / EMULSION STABILISING, SURFACTANT - CLEANSING, VISCOSITY CONTROLLING

A high-performance cationic associative polymer designed to engineer the rheological 'architecture' of advanced skincare. It is primarily utilized to create the signature 'bouncy' or elastic foam textures found in premium cleansers while providing structural reinforcement to complex emulsions.

emulsion stabilising surfactant viscosity controlling rheology modifier

Science

This ingredient operates as a hydrophobically modified 3D network. The C18-22 alkyl chains function as hydrophobic anchors that bridge oil droplets or air bubbles, while the diethylaminoethyl methacrylate (DEAEMA) groups provide a cationic charge when protonated. Together, they form a cohesive matrix in the aqueous phase that stabilizes formulations against phase separation and significantly increases foam density and elasticity.


Research

High confidence
Effective range 0.01–5%
Optimal

2.5%

Key findings

  1. 01 Korean Patent KR102556558B1: Demonstrated significant improvements in foam elasticity, density, and emulsion stability in surfactant systems without increasing skin irritation.

Transparency

Not commonly dusted
Min. effective
0.1%
Red flag below
0.05%

As a structural rheology modifier, this ingredient is rarely used for marketing 'dusting.' If present below 0.1%, it likely serves no functional purpose for texture or stabilization; however, its functional benefits are typically realized between 0.5% and 5.0%.


The Formula

Solubility
Water
Optimal pH 4.5 – 7
0 7 14

Stability

Maximum stability and thickening efficiency are achieved in slightly acidic environments (pH 4.5–6.0) where the amino groups are fully protonated, maximizing the cationic charge.

Synergies

  • Polyols (Glycerin, Butylene Glycol)
  • Mild surfactants
  • Magnesium Ascorbyl Phosphate (MAP)

Conflicts

  • High concentrations of strong anionic surfactants
  • High electrolyte/salt concentrations

Safety

CIR Status
Not reviewed
Max tested
5%
Pregnancy
Safe
Sensitization risk Low

While not individually reviewed by the CIR, the polymer's high molecular weight prevents skin penetration. Its constituent monomers are recognized as safe in polymer form. It is listed in the EU CosIng database without restrictions.


Your Skin

Yes Normal
Yes Dry
Yes Oily
Yes Sensitive
Irritancy Low
Comedogenicity Low

Our Assessment

Valuable

An essential technical ingredient for achieving superior 'bouncy' textures and foam stability in precision cleansing and emulsion systems.


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References