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BUTYL METHACRYLATE.

Avoid CAS 97-88-1 / FILM FORMING, FRAGRANCE, VISCOSITY CONTROLLING

A reactive monomer primarily used in nail products for its exceptional film-forming properties and ability to create durable, water-resistant coatings. While effective for nail enhancement applications, this ingredient presents significant irritation and sensitization concerns that limit its broader cosmetic use.

film forming viscosity controlling fragrance

Science

Functions as a reactive ester monomer that polymerizes to form flexible, protective films on surfaces. When in contact with skin, it undergoes enzymatic hydrolysis by carboxylesterases to produce methacrylic acid, while its potential for covalent protein binding creates hapten formation leading to sensitization responses.


Research

High confidence
Effective range 0.1–1.5%
Optimal

1%

Key findings

  1. 01 4-hour occluded patch testing at 100% concentration showed significant erythema (2.3/4.0 scale) with effects lasting 14 days
  2. 02 Consumer exposure modeling identified 1% as the threshold for long-term local effects and sensitization risk

Transparency

Not commonly dusted
Min. effective
1%
Red flag below
1.5%

Regulatory restrictions limit use to nail products with skin contact avoidance, making dusting practices inappropriate for this sensitizing ingredient.


The Formula

Solubility
Oil
Optimal pH 3 – 10
0 7 14

Stability

Requires polymerization inhibitors like hydroquinone and oxygen headspace to prevent spontaneous curing. Exhibits high reactivity with exothermic potential under acidic or oxidizing conditions.

Conflicts

  • Strong oxidizing agents
  • Strong acids
  • Caustic solutions
  • Alkali metals
  • UV light

Safety

CIR Status
Safe with restrictions
Max tested
1.5%
Sensitization risk High

CIR approval limited to nail enhancement products only with mandatory skin contact avoidance due to potent sensitization potential in monomeric form.


Your Skin

Yes Normal
Yes Dry
Yes Oily
No Sensitive
Irritancy High
Comedogenicity Low

Our Assessment

Avoid

Restricted to specialized nail applications due to high irritation and sensitization potential that makes it unsuitable for general skincare formulations.


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