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BROMOCINNAMAL.

Questionable CAS 5443-49-2 / FRAGRANCE

A brominated cinnamaldehyde derivative that functions as both a masking fragrance agent and experimental tyrosinase inhibitor. While showing promise for skin brightening applications through enzyme inhibition, its primary use remains in fragrance formulations where it provides masking properties.

masking fragrance ingredient

Science

Inhibits tyrosinase activity by binding to the enzyme's active site and quenching its fluorescence, thereby blocking the oxidation of L-DOPA in melanin synthesis pathways. Additionally exhibits antimicrobial effects through electrophilic interactions that disrupt bacterial cell wall integrity.


Research

Medium confidence
Effective range 0.049–0.075%
Optimal

0.06%

Key findings

  1. 01 Potent tyrosinase inhibition with IC50 values of 0.075 mM for monophenolase and 0.049 mM for diphenolase activity
  2. 02 Significant antibacterial activity against S. aureus and E. coli, outperforming unsubstituted cinnamaldehyde

Transparency

Not commonly dusted

Primarily used as a fragrance component with experimental brightening applications; not commonly used for dusting marketing claims


The Formula

Solubility
Oil
Optimal pH 4 – 7
0 7 14

Stability

Susceptible to oxidation forming 2-bromocinnamic acid under air exposure or extreme pH conditions. Requires opaque, airtight storage containers for stability maintenance.

Conflicts

  • Amines (forms Schiff bases)
  • Strong oxidizing agents
  • Nucleophilic compounds

Safety

CIR Status
Not reviewed
Max tested
0.1%
Sensitization risk High

EU Annex III listed masking agent with mandatory labeling requirements when exceeding 0.001% in leave-on products due to cinnamic derivative sensitization potential


Your Skin

Yes Normal
Yes Dry
Yes Oily
No Sensitive
Irritancy High
Comedogenicity Low

Our Assessment

Questionable

While showing theoretical promise for tyrosinase inhibition, high sensitization risk and limited clinical validation make it unsuitable for precision skincare applications.


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References