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BENZYLHEMIFORMAL.

Avoid CAS 14548-60-8 / PRESERVATIVE

Benzylhemiformal is a specialized preservative used exclusively in wash-off formulations to ensure product integrity against microbial contamination. It functions as a formaldehyde-releasing agent, providing broad-spectrum protection in high-moisture environments like cleansers and shampoos.

Preservative

Science

Upon contact with water in a formulation, Benzylhemiformal undergoes a controlled decomposition process to release small amounts of formaldehyde and benzyl alcohol. These components work in tandem: formaldehyde cross-links microbial proteins and nucleic acids to halt reproduction, while benzyl alcohol destabilizes the microbial cell membrane to increase permeability and efficacy.


Research

High confidence
Effective range 0.01–0.15%
Optimal

0.15%

Key findings

  1. 01 Scientific Committee on Cosmetic Products (SCCNFP/0587/02) confirmed its efficacy as a safe preservative in rinse-off products at concentrations up to 0.15%.
  2. 02 SCCS/1576/16 research highlights its potential as a skin sensitizer, particularly for those with existing formaldehyde allergies.

Transparency

Not commonly dusted
Min. effective
0.05%
Red flag below
0.15%

As a preservative, it is typically used at very low, regulated concentrations. Using it below 0.05% may compromise the formula's shelf life, while exceeding 0.15% violates safety regulations in many jurisdictions.


The Formula

Solubility
Water
Optimal pH 3.5 – 8
0 7 14

Stability

Highly water-miscible and stable in slightly acidic to neutral environments. It becomes unstable at a pH above 10.0, which can lead to premature or rapid decomposition.

Synergies

  • Chelating agents
  • Other non-formaldehyde-releasing co-preservatives

Conflicts

  • Primary and secondary amines
  • Amides
  • Proteins
  • Strong oxidizing agents
  • Zinc pyrithione

Safety

CIR Status
Not reviewed
Max tested
0.15%
Sensitization risk High

Strictly prohibited in aerosols and oral care products. Restricted in the EU (Annex V) and Washington State due to formaldehyde release concerns. Individuals with known formaldehyde sensitivities should avoid this ingredient.


Your Skin

Yes Normal
Yes Dry
Yes Oily
No Sensitive
Irritancy Moderate
Comedogenicity Low

Our Assessment

Avoid

While effective at microbial control, its status as a formaldehyde-releaser and its potential for sensitization make it a less desirable choice compared to modern, gentler preservative systems.


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