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BENZYL ACETOACETATE.

Optional CAS 5396-89-4 / PERFUMING

A versatile beta-keto ester that serves a dual purpose in precision skincare: providing a refined olfactory profile while acting as a targeted sensory modulator. Its unique chemical structure allows it to provide a specific non-thermal cooling effect, making it a sophisticated alternative to traditional cooling agents.

Perfuming Masking Sensory cooling agent Chemical intermediate

Science

This ingredient functions as an agonist for the Transient Receptor Potential Melastatin 8 (TRPM8) ion channel. By stimulating these cold-sensitive sensory neurons, it triggers a perceived cooling sensation on the skin's surface without inducing an actual drop in tissue temperature or causing the irritation sometimes associated with high concentrations of menthol.


Research

Medium confidence
Effective range 1–10%
Optimal

1%

Key findings

  1. 01 Evaluation of bioactive TRPM8 modulation for non-thermal skin cooling (US Patent 2017/0087199 A1)
  2. 02 IFRA-derived olfactory stability and fragrance profile assessment (The Good Scents Company)

Transparency

Commonly dusted
Min. effective
1%
Red flag below
0.1%

In many commercial formulas, this ingredient is included at negligible concentrations (under 0.1%) simply to mask base odors. To achieve its functional bioactive cooling effect, a concentration of at least 1.0% is required.


The Formula

Solubility
Oil
Optimal pH 1 – 5
0 7 14

Stability

Exhibits maximum stability in acidic environments; highly susceptible to hydrolysis in alkaline conditions or high-water-content formulations which can degrade the ester into benzyl alcohol.

Synergies

  • Acidic stabilizers
  • Oil-based delivery systems
  • Other TRPM8 modulators

Conflicts

  • Strong bases
  • Strong oxidizing agents
  • High-alkalinity environments
  • Aqueous formulas intended for long-term shelf storage

Safety

CIR Status
Not reviewed
Max tested
10%
Pregnancy
Safe
Sensitization risk Low

Recognized as GRAS (Generally Recognized as Safe) by FEMA (#2136) and FDA-approved for food flavoring. While concentrated forms are irritants, it is considered safe and non-sensitizing at the levels typically utilized in cosmetic applications.


Your Skin

Yes Normal
Yes Dry
Yes Oily
No Sensitive
Irritancy Low
Comedogenicity Low

Our Assessment

Optional

An excellent sensory additive for acidic formulations requiring a sophisticated cooling effect without the harshness of menthol.


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