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BEHENAMIDOPROPYL BETAINE.

Valuable CAS 138527-93-2 / CLEANSING, SURFACTANT - CLEANSING, SURFACTANT - FOAM BOOSTING

A sophisticated, long-chain amphoteric surfactant derived from behenic acid that bridges the gap between cleansing and conditioning. It is engineered to provide an exceptionally smooth skin feel while enhancing the stability and texture of precision skincare formulations.

Surfactant Foam Booster Skin Conditioner Hair Conditioner Viscosity Increasing Agent

Science

As a zwitterionic molecule with a C22 behenyl tail, it works by forming mixed micelles with harsher anionic surfactants. This process increases the overall size of the micelles, preventing them from penetrating the skin barrier and significantly reducing the irritation potential of the cleansing system. Additionally, its long-chain structure deposits a microscopic, non-greasy lubricating film that provides antistatic and conditioning benefits.


Research

High confidence
Effective range 0.5–10%
Optimal

3%

Key findings

  1. 01 Safety assessments by the CIR (2012) established a 3.0% maximum active concentration for leave-on products to mitigate sensitization risks from manufacturing by-products.
  2. 02 Ocular and dermal testing on animal models using a 10% active solution (pH 6.1) demonstrated a Primary Irritation Index (PII) of 0.25, classifying it as non-irritating.

Transparency

Not commonly dusted
Min. effective
0.5%
Red flag below
0.1%

Because it is often used as a secondary surfactant or a co-emulsifier, it is rarely 'dusted' at purely symbolic levels. However, in leave-on products, concentrations exceeding 3% active matter may indicate a lack of adherence to safety guidelines regarding potential impurities.


The Formula

Solubility
Water
Optimal pH 4.5 – 8
0 7 14

Stability

Highly stable across a wide pH range and compatible with anionic, cationic, and non-ionic systems, making it a versatile choice for complex '2-in-1' textures.

Synergies

  • Sodium Laureth Sulfate
  • Sodium Cocoyl Isethionate
  • Glycerin

Safety

CIR Status
Safe as used
Max tested
3%
Pregnancy
Safe
Sensitization risk Low

While safe for rinse-off use at various levels, leave-on formulations are restricted to 3.0% to prevent potential sensitization from DMAPA or amidoamine impurities.


Your Skin

Yes Normal
Yes Dry
Yes Oily
Yes Sensitive
Irritancy Low
Comedogenicity Low

Our Assessment

Valuable

An excellent secondary surfactant for creating high-performance, low-irritation cleansers that leave a tangible conditioning effect on the skin.


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References