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BEHENALKONIUM CHLORIDE.

Valuable CAS 16841-14-8 / ANTISTATIC, HAIR CONDITIONING, SURFACTANT - CLEANSING

A high-performance cationic surfactant and antimicrobial agent derived from long-chain behenyl fatty acids. It serves as a dual-action ingredient that provides substantive conditioning to the skin barrier while maintaining product hygiene through potent surface-cleansing properties.

antimicrobial conditioning agent antistatic surfactant preservative booster

Science

As a quaternary ammonium compound, it utilizes a positively charged nitrogen head to anchor itself to negatively charged surfaces like skin and microbial cell walls. Its long C22 alkyl chain then integrates into lipid structures; in microbes, this causes membrane leakage, while on the skin, it forms a protective, antistatic film that enhances smoothness and texture.


Research

High confidence
Effective range 0.01–5%
Optimal

0.1%

Key findings

  1. 01 Validated by the FDA as an effective broad-spectrum antimicrobial concentration for first-aid antiseptic use.
  2. 02 Significantly improves skin texture and manageability in rinse-off applications by creating a smooth after-feel.

Transparency

Commonly dusted
Min. effective
0.01%
Red flag below
0.005%

Because it functions as an antimicrobial even at ultra-low concentrations (below 0.1%), brands may include it primarily as a preservative while marketing its 'conditioning' benefits, which typically require concentrations closer to 1% to be perceivable by the user.


The Formula

Solubility
Water
Optimal pH 4 – 9
0 7 14

Stability

Extremely heat-stable up to 121°C; however, it may exhibit a slight decline in pH and potency over a 12-month period if not properly buffered.

Synergies

  • Non-ionic surfactants
  • Cationic conditioners
  • Fatty alcohols

Conflicts

  • Anionic surfactants (SLS/SLES)
  • Carbomers
  • Acrylate crosspolymers
  • Soap-based cleansers
  • Oxidizing agents

Safety

CIR Status
Insufficient data
Max tested
0.1%
Sensitization risk Moderate

Current 2025 CIR reviews request further data on impurities. Safety benchmarks are often drawn from its analog, Benzalkonium Chloride, which is capped at 0.1% for leave-on applications.


Your Skin

Yes Normal
Yes Dry
Yes Oily
No Sensitive
Irritancy Moderate
Comedogenicity Low

Our Assessment

Valuable

A highly effective conditioning and antimicrobial agent that excels in specialized acne and texture treatments, provided it is formulated away from anionic triggers.


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