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BASIC RED 46.

Avoid CAS 12221-69-1 / HAIR DYEING

A cationic azo dye primarily used in industrial textile and hair coloring applications. Due to its high sensitization potential and regulatory restrictions, it is not utilized in modern precision skincare formulations.

hair dyeing industrial colorant

Science

As a positively charged molecule, it bonds ionically to negatively charged surfaces like keratin in hair or synthetic acrylic fibers. While it exhibits poor transdermal penetration, it acts as a potent hapten, frequently triggering Type IV hypersensitivity reactions upon skin contact.


Research

High confidence
Effective range 1–2%
Optimal

0%

Key findings

  1. 01 Identified as a major contact allergen in textile-related dermatitis cases, accounting for over 20% of positive reactions in specialized dye testing.
  2. 02 Clinical patch testing confirmed strong positive reactions and significant cross-reactivity with p-Phenylenediamine (PPD).

Transparency

Not commonly dusted
Min. effective
0.1%
Red flag below
0.01%

This ingredient is prohibited in many regions; any presence in topical skincare is a significant safety concern rather than a 'dusting' issue.


The Formula

Solubility
Water
Optimal pH 3 – 6.5
0 7 14

Stability

Maintains high thermal stability up to 130°C and remains stable in acidic environments, though its cationic nature makes it highly reactive in certain mixtures.

Conflicts

  • Anionic surfactants
  • Strong oxidizing agents
  • Strong reducing agents

Safety

CIR Status
Not reviewed
Max tested
0%
Pregnancy
Caution
Sensitization risk High

Explicitly prohibited for cosmetic use in the European Union (Annex II, Ref. No. 1259). Classified as a GHS Category 1 substance for serious eye damage.


Your Skin

No Normal
No Dry
No Oily
No Sensitive
Irritancy High
Comedogenicity Unknown

Our Assessment

Avoid

Strictly prohibited in quality skincare due to its classification as a potent skin sensitizer and regulatory bans in major markets.


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