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AMMONIUM THIOGLYCOLATE.

Valuable CAS 5421-46-5 / DEPILATORY, HAIR WAVING OR STRAIGHTENING, REDUCING

Ammonium thioglycolate is a reducing agent primarily utilized for its ability to break disulfide bonds in hair. It is a key component in hair modification products, including depilatories and permanent wave solutions.

reducing hair waving or straightening depilatory

Science

This ingredient acts by reducing disulfide (cystine) bonds in the hair's keratin structure, transforming them into cysteine residues. This process weakens the protein cross-links, enabling hair reshaping or removal.


Research

High confidence
Effective range N/A
Optimal

N/A

Key findings

  1. 01 Single and repeated applications of 6.5% concentration did not induce skin irritation in normal subjects (Journal of the American College of Toxicology 1991).
  2. 02 Single applications of 7.0% concentration did not induce skin irritation, though higher concentrations and basic formulations were noted as potential irritants (NTP Technical Report 2009 / CIR).

Transparency

Not commonly dusted

Ammonium thioglycolate is an active chemical agent used for specific functional purposes in concentrations that are not conducive to dusting practices.


The Formula

Solubility
Water
Optimal pH 7 – 12.7
0 7 14

Stability

Existing in equilibrium with thioglycolic acid and ammonia, highly alkaline environments (pH 9.0-10.5) are essential for its effective disulfide bond cleavage.

Conflicts

  • Acids (releases toxic hydrogen sulfide gas)
  • Oxidizing agents (neutralizes the reducing effect)
  • Metals (corrosive to metals)

Safety

CIR Status
Safe with restrictions
Max tested
15.2%
Sensitization risk Moderate

This ingredient is deemed safe at concentrations up to 15.2% (calculated as thioglycolic acid) in hair products. EU/SCCS limits it to 8% for general hair use, 11% for professional hair use, and 5% for depilatories, requiring minimized skin contact.


Your Skin

Yes Normal
No Dry
Yes Oily
No Sensitive
Irritancy Medium
Comedogenicity Low

Our Assessment

Valuable

Ammonium thioglycolate is a valuable ingredient for its specific, highly effective hair-modifying properties, but its use requires strict adherence to concentration limits and careful formulation due to its potential irritancy.


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