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ALUMINUM CHLORIDE.

Valuable CAS 7446-70-0 / ANTIPERSPIRANT, ASTRINGENT, DEODORANT

Aluminum Chloride is a highly effective antiperspirant agent, primarily utilized to manage excessive sweating (hyperhidrosis). It reduces sweat production by temporarily blocking sweat ducts.

antiperspirant astringent

Science

This ingredient forms a physical gel matrix or plug within the distal sweat gland ducts. Metal ions precipitate with mucopolysaccharides, causing epithelial cell damage that obstructs sweat flow.


Research

High confidence
Effective range 1–20%
Optimal

15%

Key findings

  1. 01 Clinical trials demonstrate that 15% concentrations are as effective as 20% for axillary hyperhidrosis, with significantly better patient tolerability and reduced irritation.
  2. 02 Iontophoresis of 1% aluminum chloride hexahydrate induced significant hypohidrosis lasting 4 weeks without reported side effects.

Transparency

Not commonly dusted

The Formula

Solubility
Water
Optimal pH 1.9 – 4
0 7 14

Stability

Highly hygroscopic, it reacts with water to form hydrochloric acid, a known irritant. It remains stable in anhydrous ethanol or acidic aqueous solutions, but hydrolysis increases above pH 4.0.

Conflicts

  • Bases
  • Strong oxidizers
  • Alkali metals
  • Water (reacts exothermically in anhydrous form)
  • Most metals (corrosive)

Safety

CIR Status
Not reviewed
Max tested
15%
Sensitization risk Moderate

The FDA OTC monograph permits up to 15% (as hexahydrate) in non-aerosol solutions. While SCCS deems aluminum compounds safe at specified levels, concentrated aluminum chloride is a known skin irritant and potential allergen.


Your Skin

Yes Normal
No Dry
Yes Oily
No Sensitive
Irritancy High
Comedogenicity Low

Our Assessment

Valuable

Aluminum Chloride is a highly effective ingredient for managing hyperhidrosis, yet its potential for high irritancy necessitates careful formulation and use, especially for sensitive skin types.


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