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ALLYL METHACRYLATE.

Valuable CAS 96-05-9 / NOT REPORTED

Allyl Methacrylate functions as a cross-linking agent, forming porous polymer microspheres in skincare formulations. These structures enable controlled release of actives or absorb excess sebum for a matte finish.

viscosity controlling absorbent film forming cross-linking agent

Science

It creates bridging connections between polymer chains, forming micro-sponge-like structures. These microspheres can encapsulate active ingredients or act as high-capacity absorbents for skin oils.


Research

Medium confidence
Effective range N/A
Optimal

N/A

Key findings

  1. 01 Formulations incorporating up to 2.6% of related crosspolymers (which utilize Allyl Methacrylate as a crosslinker) demonstrated no dermal irritation or sensitization in HRIPT tests, indicating safety within its functional role.

Transparency

Not commonly dusted

The Formula

Solubility
Oil
Optimal pH 3 – 9
0 7 14

Stability

The monomer is sparingly water-soluble but highly soluble in organic solvents. The resulting polymer is generally insoluble but stable across a wide pH range, though the monomer itself is sensitive to high heat and UV.

Conflicts

  • Strong oxidizing agents
  • Strong bases
  • Free radical initiators (which may cause unintended polymerization)

Safety

CIR Status
Safe as used
Max tested
4%
Sensitization risk Low

The CIR Expert Panel concluded crosslinked alkyl acrylates, incorporating Allyl Methacrylate, are safe for use. This safety is contingent on proper polymerization (non-benzene solvents, <1-2 ppm residual monomer); undiluted Allyl Methacrylate is a potent irritant and sensitizer.


Your Skin

Yes Normal
Yes Dry
Yes Oily
Yes Sensitive
Irritancy Low
Comedogenicity Low

Our Assessment

Valuable

This ingredient is valuable for enhancing product texture and facilitating controlled active delivery through its unique polymer-forming capabilities, provided it is used in its safely polymerized form.


Related

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References