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ACRYLATES/CETEARETH-25 METHACRYLATE/METHACRYLAMIDE CROSSPOLYMER.

Valuable / HAIR FIXING

This hydrophobically modified alkali-swellable emulsion (HASE) polymer primarily functions as a viscosity controller and film-forming agent. It enhances the texture and stability of skincare and cosmetic formulations.

viscosity controlling film forming hair fixing

Science

It acts as an associative thickener, where hydrophobic ceteareth-25 chains form physical crosslinks with non-polar components. The acrylate backbone provides a salt-tolerant thickening network upon neutralization, optimizing rheology.


Research

Medium confidence
Effective range 0.1–1%
Optimal

N/A

Key findings

  1. 01 Studies indicate that HASE polymers with ceteareth-25 methacrylate effectively modify rheology and control viscosity in aqueous alkaline systems, even at low concentrations (0.1% - 1.0%).

Transparency

Not commonly dusted

The Formula

Solubility
Water
Optimal pH 6 – 12
0 7 14

Stability

Requires neutralization with a base (e.g., NaOH, TEA) to initiate thickening. It remains stable in high-surfactant environments and is compatible with numerous cosmetic oils and silicones.

Synergies

  • Cosmetic oils
  • Silicones
  • Surfactants

Conflicts

  • Low pH systems (below 6.0)
  • High concentrations of electrolytes/salts
  • Cationic ingredients

Safety

CIR Status
Safe as used
Max tested
25%
Sensitization risk Low

Reviewed as part of the broader 'Acrylates Copolymers' group. Safe when formulated to be non-irritating and residual monomers like methacrylamide are kept below 100 ppm.


Your Skin

Yes Normal
Yes Dry
Yes Oily
Yes Sensitive
Irritancy Low
Comedogenicity Low

Our Assessment

Valuable

A valuable viscosity-controlling and film-forming polymer, compatible with all skin types and effective at low concentrations, enhancing product texture and stability.


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