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ACRYLATES/BEHENETH-25 METHACRYLATE/HEMA CROSSPOLYMER.

Valuable / EMULSION STABILISING, FILM FORMING, HAIR FIXING, VISCOSITY CONTROLLING

This versatile crosspolymer serves as a rheology modifier, emulsion stabilizer, and film-forming agent, crucial for optimizing product texture and ensuring formulation integrity. It enables precise viscosity control and enhances the stability of diverse cosmetic products.

viscosity controlling emulsion stabilising film forming

Science

Operating via an alkali-swellable mechanism, its carboxylic acid groups ionize above pH 6, causing polymer chains to uncoil and expand due to electrostatic repulsion. This creates a high-viscosity network that effectively suspends particles and stabilizes oil-in-water emulsions by forming structural barriers.


Research

High confidence
Effective range 0.05–1.7%
Optimal

0.3%

Key findings

  1. 01 Typical usage in leave-on products effectively modifies rheology and stabilizes emulsions without significant skin irritation.
  2. 02 Effective in rinse-off products for viscosity control and maintaining formulation stability.

Transparency

Not commonly dusted

The Formula

Solubility
Water
Optimal pH 6 – 8
0 7 14

Stability

Requires neutralization with a base to achieve an optimal pH of 6-8 for maximum thickening and clarity, as it exhibits low viscosity at low pH. It remains stable in the presence of UV light and oxygen.

Conflicts

  • Low pH environments (< 5.5) leading to precipitation
  • High concentrations of electrolytes/salts which can collapse the polymer network
  • Cationic surfactants or polymers

Safety

CIR Status
Safe as used
Max tested
1.7%
Sensitization risk Low

The CIR Expert Panel concludes safety when formulated to be non-irritating. Key safety considerations include avoiding polymerization in benzene and minimizing residual HEMA monomer to prevent potential sensitization.


Your Skin

Yes Normal
Yes Dry
Yes Oily
Yes Sensitive
Irritancy Low
Comedogenicity Low

Our Assessment

Valuable

This crosspolymer is a valuable ingredient for formulation stability and texture enhancement, demonstrating high safety and broad skin compatibility across various product types.


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References