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ACETYL HISTIDINE.

Valuable CAS 2407-02-1 / 39145-52-3 / HUMECTANT, SKIN CONDITIONING, SKIN CONDITIONING - EMOLLIENT

Acetyl Histidine is a versatile amino acid derivative that profoundly enhances skin health through multi-faceted actions. It actively supports collagen production for improved skin firmness and texture, while acting as a potent antioxidant to defend against environmental aggressors. Additionally, it boosts skin hydration, aids in cell repair and renewal, and strengthens the skin's natural protective barrier.

Antioxidant Humectant Skin Barrier Support Collagen Boosting Cell Repair and Renewal Skin Tone Balancing Reduction of Hyperpigmentation Oil Regulation Indirect UV Protection Anti-aging

Science

As an acetylated derivative of Histidine, Acetyl Histidine contributes significantly to dermal well-being. It stimulates collagen synthesis, leading to firmer skin and a visible reduction in the appearance of wrinkles. Functioning as a robust antioxidant, it neutralizes free radicals generated by external stressors like pollution and UV radiation. Its humectant properties attract and retain moisture, effectively hydrating the skin and minimizing the prominence of fine lines. This ingredient also fosters cellular repair and renewal processes, resulting in improved skin texture, more balanced tone, and diminished visibility of age spots and hyperpigmentation. Crucially, it fortifies the skin barrier, enhancing its ability to retain moisture and shield against drying environmental factors. Furthermore, Acetyl Histidine contributes to maintaining the skin's natural pH balance, which in turn helps regulate oil production. Its precursor, L-Histidine, is vital for producing filaggrin, a key protein for skin barrier integrity, and forms part of the Natural Moisturizing Factor (NMF). L-Histidine is also converted into urocanic acid (UCA) in the epidermis, a natural UV-absorbing compound offering indirect photoprotection. Acetyl Histidine itself directly participates in protein synthesis and offers a potential antioxidant effect.


Research

Medium confidence
Effective range N/A
Optimal

N/A

Key findings

  1. 01 Oral L-Histidine at 0.8 g daily reduced eczema area and severity index scores by 49% over 12 weeks in young children with atopic dermatitis.
  2. 02 Oral L-Histidine at 4 g daily in adults with atopic dermatitis resulted in a 34% reduction in SCORAD scores over 4 weeks and a 32% reduction over 8 weeks, concurrently decreasing topical corticosteroid use by 33%.

Transparency

Not commonly dusted

The Formula

Solubility
Both
Optimal pH 5.5 – 7.5
0 7 14

Stability

Acetylation significantly improves the solubility and stability of histidine. It functions effectively as a buffering agent, particularly within the pH range of 5.5–6.5. The His+ form exhibits optimal stability below pH 7.5. Formulations containing high concentrations of histidine should avoid prolonged storage in stainless steel containers at elevated temperatures (40°C) to prevent potential discoloration and aggregation. Degradation into trans-urocanic acid, potentially triggered by Manganese (Mn(2+)) contamination, can be substantially mitigated (by 97-98%) through the inclusion of chelating agents such as EDTA or DTPA, or by adding alanine or cysteine.

Synergies

  • Chelating agents (EDTA, DTPA)
  • Alanine
  • Cysteine

Conflicts

  • High concentrations in stainless steel containers at 40°C
  • Contamination with Manganese (Mn(2+))

Safety

CIR Status
Safe as used
Sensitization risk Low

The Cosmetic Ingredient Review (CIR) has concluded that Acetyl Histidine is safe for use in cosmetics under current practices and concentrations, provided formulations are non-irritating. While PubChem lists general GHS hazard statements for the raw chemical N-Acetyl-L-histidine (e.g., 'Causes skin irritation,' 'May cause an allergic skin reaction'), these warnings pertain to the concentrated raw substance and do not reflect its safety profile when properly formulated in cosmetic products at typical usage levels.


Your Skin

Yes Normal
Yes Dry
Yes Oily
Yes Sensitive
Irritancy Unknown
Comedogenicity Unknown

Our Assessment

Valuable

Acetyl Histidine is a valuable multi-functional ingredient that significantly supports skin barrier integrity, hydration, and anti-aging processes, making it beneficial for all skin types.


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