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4-NITRO-O-PHENYLENEDIAMINE SULFATE.

Questionable CAS 68239-82-7 / HAIR DYEING

A synthetic aromatic amine compound primarily utilized as a direct dye and oxidative coupler in hair coloring formulations. This water-soluble sulfate salt form demonstrates controlled penetration properties while maintaining stability under standard conditions, though it requires careful handling due to its known sensitization potential.

hair dyeing direct dye oxidative coupler

Science

Functions through dual pathways: as a direct dye, its compact molecular structure enables diffusion into hair cuticles, while in oxidative systems it acts as a coupler, reacting with aromatic amines in the presence of hydrogen peroxide to create larger, stable pigment molecules that become trapped within the hair matrix.


Research

High confidence
Effective range 0.1–0.5%
Optimal

0.5%

Key findings

  1. 01 SCCP 2006 assessment demonstrated Margin of Exposure of 357 at 0.5% concentration with NOAEL of 15 mg/kg bw/d
  2. 02 CIR repeated insult patch testing on 206 subjects at 0.1-0.2% showed no adverse irritation
  3. 03 2024 dermal penetration studies confirmed systemic absorption of 0.83 ± 0.69 µg eq/cm² at 0.2-0.29%

Transparency

Not commonly dusted
Min. effective
0.1%
Red flag below
0.5%

Regulated ingredient with established maximum concentrations; presence above 0.5% would indicate non-compliance with European safety standards


The Formula

Solubility
Water
Optimal pH 6 – 7
0 7 14

Stability

Maintains stability under standard conditions but exhibits photosensitivity requiring light protection; sulfate salt enhances water solubility compared to free base form

Synergies

  • hydrogen peroxide
  • aromatic amines
  • aqueous alcoholic solutions

Conflicts

  • strong oxidizing agents
  • strong acids
  • strong reducing agents
  • acid chlorides
  • acid anhydrides

Safety

CIR Status
Safe as used
Max tested
0.5%
Sensitization risk High

European Annex III restricts maximum hair application to 0.5% post-oxidative mixing; classified as known skin sensitizer requiring appropriate precautions


Your Skin

Yes Normal
Yes Dry
Yes Oily
No Sensitive
Irritancy Low
Comedogenicity Unknown

Our Assessment

Questionable

While technically safe at regulated concentrations for hair applications, its high sensitization potential and specialized hair-dyeing function make it unsuitable for precision skincare formulations.


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