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4-NITRO-M-PHENYLENEDIAMINE SULFATE.

Avoid CAS - / HAIR DYEING

A synthetic chemical compound primarily used as a dye precursor in oxidative hair coloring systems. This water-soluble sulfate salt functions as a coupling agent that combines with hydrogen peroxide to create permanent color molecules within the hair shaft.

hair dyeing dye precursor colorant coupler

Science

Functions as a dye coupler that diffuses into hair follicles and reacts with hydrogen peroxide to form larger aza dye molecules that become trapped within the hair structure, creating permanent coloration


Research

High confidence
Effective range 0.5–3%
Optimal

0.5%

Key findings

  1. 01 SCCS Opinion 2006 demonstrated safety at 0.5% concentration in oxidative hair dye formulations
  2. 02 Journal of American College of Toxicology 1992 showed high sensitization potential at 3.0% in guinea pig studies
  3. 03 CIR Safety Assessment 2024 confirmed non-irritating properties at 2.5% concentration

Transparency

Not commonly dusted
Red flag below
3%

Not applicable to skincare dusting as this ingredient is exclusively used in hair dye formulations, not facial skincare products


The Formula

Solubility
Water
Optimal pH 6 – 7
0 7 14

Stability

Sulfate salt form provides enhanced stability compared to free base. Requires protection from air exposure to prevent oxidative degradation and discoloration. pH neutralization to 6-7 range optimizes stability.

Synergies

  • hydrogen peroxide
  • other hair dye couplers

Conflicts

  • Strong oxidizing agents
  • Strong acids
  • Iron and metal ions

Safety

CIR Status
Safe with restrictions
Max tested
0.5%
Sensitization risk High

CIR Panel confirms safety for hair dye applications in non-sensitized individuals at ≤0.5%. Known skin sensitizer with high allergenic potential. Insufficient safety data for airbrush delivery methods.


Your Skin

Yes Normal
Yes Dry
Yes Oily
No Sensitive
Irritancy Low
Comedogenicity Unknown

Our Assessment

Avoid

High sensitization risk and restriction to hair-only applications make this ingredient unsuitable for precision skincare formulations.


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