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4-CHLORO-2-AMINOPHENOL.

Avoid CAS 95-85-2 / HAIR DYEING

A synthetic aromatic compound primarily developed as an oxidative hair dye precursor that forms colored pigment molecules when activated by hydrogen peroxide. While approved for restricted hair coloring applications, this ingredient carries significant safety concerns including potential carcinogenicity and mutagenicity classified as IARC Group 2B.

hair colouring

Science

Functions by penetrating the hair shaft where it undergoes oxidative coupling with hydrogen peroxide to create large, trapped pigment molecules within the hair cortex, though its mechanism on skin tissue involves potential cellular DNA damage through mutagenic pathways


Research

High confidence
Effective range N/A
Optimal

N/A

Key findings

  1. 01 Two-year rodent studies at 512-8000 ppm demonstrated increased forestomach carcinomas and urinary bladder tumors
  2. 02 Human patch testing showed no primary irritation in control subjects despite sensitization potential

Transparency

Not commonly dusted

Not applicable for skincare formulations due to regulatory restrictions and safety profile


The Formula

Solubility
Water
Optimal pH N/A
0 7 14

Stability

Light brown crystalline solid requiring protection from prolonged air and light exposure; maintains stability under standard conditions but degrades with environmental exposure

Conflicts

  • Strong oxidizing agents
  • Strong acids
  • Strong bases
  • Iron
  • Moisture

Safety

CIR Status
Safe with restrictions
Pregnancy
Caution
Sensitization risk Moderate

Banned in European Union under Annex II regulations and listed under California Proposition 65 as a carcinogen; CIR approval limited exclusively to oxidative hair dye applications with insufficient data for other cosmetic uses


Your Skin

No Normal
No Dry
No Oily
No Sensitive
Irritancy Unknown
Comedogenicity Unknown

Our Assessment

Avoid

This ingredient should be avoided in precision skincare due to its carcinogenic classification, regulatory restrictions, and lack of demonstrated skin benefits.


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