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2-HYDROXYPROPYL ACRYLATE.

Questionable CAS 999-61-1; 25584-83-2 / FILM FORMING

2-Hydroxypropyl acrylate is a highly restricted acrylic monomer that appears in cosmetic formulations only as trace residual content from polymer synthesis. This water-miscible compound is primarily valued for its crosslinking and film-forming capabilities, though its severe irritant properties limit its direct use in skincare applications. When present in finished products, it typically exists at extremely low concentrations as an incidental component rather than an active ingredient.

film former viscosity controlling adhesive crosslinking agent

Science

Functions as a crosslinking agent that provides hydroxyl functional groups to polymer structures, enhancing hydrophilicity and skin adhesion properties. The hydroxyl groups facilitate water retention and contribute to film formation on the skin surface, though these benefits are only realized when the compound is incorporated into larger polymer networks that neutralize its irritant potential.


Research

Medium confidence
Effective range ≤0.5%
Optimal

N/A

Key findings

  1. 01 NIH dermal permeation study (2011) demonstrated non-linear skin penetration behavior with dehydration effects at high concentrations
  2. 02 NIOSH safety study (1981) documented severe skin necrosis from undiluted exposure, establishing toxicity profile

Transparency

Not commonly dusted
Min. effective
0.5%
Red flag below
0.1%

Due to its severe irritant properties and regulatory restrictions, any concentration above 0.5 ppm raises significant safety concerns. Brands using higher concentrations would face serious formulation and safety challenges.


The Formula

Solubility
Water
Optimal pH 3 – 7
0 7 14

Stability

Exhibits exceptional pH-dependent stability with half-lives exceeding 490 days at pH 3 and 230 days at pH 7, but rapidly degrades in alkaline conditions. Requires oxygen presence for stabilizer function and to prevent spontaneous polymerization reactions.

Conflicts

  • Inert gas environments
  • High temperatures above 35°C
  • Strong alkaline compounds
  • Free radical initiators

Safety

CIR Status
Safe as used
Max tested
0.5%
Sensitization risk High

CIR Expert Panel approval applies specifically to trace residual levels in copolymer formulations, not direct use as an active ingredient. The monomer form exhibits severe corrosive and irritant properties requiring strict concentration controls.


Your Skin

No Normal
No Dry
No Oily
No Sensitive
Irritancy High
Comedogenicity Unknown

Our Assessment

Questionable

A technically functional but highly restricted ingredient that offers minimal consumer benefits while posing significant safety concerns at effective concentrations.


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