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2,5-XYLENOL.

Questionable CAS 95-87-4 / PERFUMING

A phenolic compound primarily utilized as an oxidative coupler in permanent hair coloring systems, where it creates bluish-purple pigments through chemical reactions with primary intermediates. Though possessing antiseptic properties characteristic of phenolic compounds, its high irritation potential and specialized alkaline pH requirements limit its application in general skincare formulations.

hair dyeing perfuming

Science

Functions as an oxidative coupler by reacting with primary intermediates like p-phenylenediamine in the presence of hydrogen peroxide to form large-molecule pigment polymers that become trapped within hair shafts. Its phenolic structure also provides mild antiseptic activity through disruption of microbial cell membranes.


Research

Medium confidence
Effective range 0.1–1%
Optimal

N/A

Key findings

  1. 01 CIR safety assessment demonstrating effective coupling action at 0.1-1.0% in oxidative hair dye systems

Transparency

Not commonly dusted

Specialized ingredient primarily used in hair dye applications rather than general cosmetic formulations


The Formula

Solubility
Both
Optimal pH 9 – 10.5
0 7 14

Stability

Requires alkaline conditions for optimal reactivity, with pKa around 10.22-10.41. Hygroscopic nature necessitates storage under inert gas and protection from light exposure.

Synergies

  • p-phenylenediamine
  • hydrogen peroxide

Conflicts

  • Strong oxidizing agents
  • Strong acids
  • Copper and brass alloys
  • Aluminium

Safety

CIR Status
Safe as used
Max tested
1%
Sensitization risk High

CIR panel deems safe for hair dye applications but explicitly unsafe for dermal coloring or eye area use. Known skin irritant and sensitizer in concentrated form.


Your Skin

No Normal
No Dry
No Oily
No Sensitive
Irritancy High
Comedogenicity Unknown

Our Assessment

Questionable

High irritation potential and specialized alkaline requirements make this ingredient unsuitable for precision skincare applications.


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